The rear sensors are just normal generic bosch 4 wire sensors that have a volvo specific plug on them
https://www.ebay.com.au/itm/O2-sensor-Universal-4-wire-with-instructions-EGO-Oxygen-Lambda-Bosch-EGO-004/153772794280?epid=244957639&hash=item23cd92a1a8:g:udoAAOSw8JxetQ74:sc:AU_RegularParcelWithTrackingAndSignature!2148!AU!-1&frcectupt=true
Otherwise, just probe the existing sensors with the car running
You should be getting sub 100mv, if you see something fluctuating between .1-1v that means the cat is dead, if you see something over 1v it means that the O2 has failed and the heater circuit is flowing electrons into the sensor circuit